As others have said charity shops are definitely a good choice. Here’s two websites that list ethical/environmentally councious clothing companies if you do want to shop brand new:
https://www.ethicalconsumer.org/fashion-clothing/a-to-z-ethical-fashion-brands
https://thegoodshoppingguide.com/subject/ethical-fashion-retailers/
As others have said charity shops are definitely a good choice. Here’s two websites that list ethical/environmentally councious clothing companies if you do want to shop brand new:
https://www.ethicalconsumer.org/fashion-clothing/a-to-z-ethical-fashion-brands
https://thegoodshoppingguide.com/subject/ethical-fashion-retailers/